Ultra-small Metal Particles for the Storage and Conversion of CO2, CH4 and H2
Advanced Functional Hybrid Materials Laboratory
2013-2016
PUBLICATIONS
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P. Á. Szilágyi, P. Serra Crespo, J. Gascon, H. Geerlings and B. Dam, The Impact of Post-Synthetic Linker Functionalization of MOFs on Methane Storage: the Role of Defects, Frontiers in Energy Research, 2016, 4, 9:1-6
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D. E. Coupry, J. Butson, P. S. Petkov, M. Saunders, K. O'Donnell, H. Kim, C. Buckley, M. Addicoat, T. Heine and P. Á. Szilágyi, Controlling embedment and surface chemistry of nanoclusters in metal–organic frameworks, Chemical Communications, 2016, 52, 5175-5178
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E. Callini, P. Á. Szilágyi, M. Paskevicius, N. P. Stadie, J. Réhault, C. E. Buckley, A. Borgschulte and A. Züttel, Stabilization of Volatile Ti(BH4)3 by Nano-Confinement in a Metal-Organic Framework, Chemical Science, 2016, 6, 666-672
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P. Á. Szilágyi, R. J. Westerwaal, M. Lansink, H. I. van Montfort, B. J. Trześniewski, M. Victoria Garcia, H. Geerlings and B. Dam, Contaminant-resistant MOF-Pd composite for H2 separation, RSC Advances, 2015, 5, 89323-89326
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P. Á. Szilágyi, I. Weinrauch, J. Juan-Alcañiz, P. Serra-Crespo, A. Grzech, H. Oh, M. de Respinis, B. J. Trześniewski, F. Kapteijn, R. van de Krol, H. Geerlings, J. Gascon, M. Hirscher and B. Dam, Interplay of linker functionalization and hydrogen adsorption in the metal-organic framework MIL-101, Journal of Physical Chemistry C, 2014, 118, 19572-19579
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P. Á. Szilágyi, E. Callini, A. Anastasopol, C. Kwakernaak, S. Sachdeva, R. van de Krol, H. Geerlings, A. Borgschulte, A. Züttel and B. Dam, Probing hydrogen spillover in Pd@MIL-101(Cr) with a focus on hydrogen chemisorption, Physical Chemistry Chemical Physics, 2014, 16, 5803-5809
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P. Á. Szilágyi, R. J. Westerwaal, R. van de Krol, H. Geerlings and B. Dam, Metal-organic framework thin film for protective coating of Pd-based optical hydrogen sensors, Journal of Materials Chemistry C, 2013, 1, 8146 - 8155
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P. Á. Szilágyi, P. Serra-Crespo, I. Dugulan, J. Gascon, H. Geerlings and B. Dam, Post-synthetic cation exchange in the robust metal-organic framework MIL-101(Cr), Crystal Engineering Communications, 2013, 15, 10175 - 10178
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P. Á. Szilágyi, M. Lutz, J. Gascon, J. Juan-Alcañiz, J. van Esch, F. Kapteijn, H. Geerlings, B. Dam and R. Van De Krol, MOF@MOF core-shell vs. Janus particles and the effect of strain: Potential for guest sorption, separation and sequestration, Crystal Engineering Communications, 2013, 15, 6003-6008
Manuscripts in peer-reviewed journals
2008-2012
2005-2007
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A. V. Gromov, N. Gray, P. Á. Szilágyi and E. E. B. Campbell, Direct grafting of carbon nanotubes with ethylenediamine, Journal of Materials Chemistry, 2012, 22, 21242-21248
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S. Cobo, G. Molnár, F. Carcenerac, P. Á. Szilágyi, L. Salmon, C. Vieu, A. Bousseksou, Assembly, patterning and properties of Prussian blue thin films, Journal of Nanoscience and Nanotechnology 2010, 8, 5042-5050
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C. Faulmann, P. Á. Szilágyi, K. Jacob, J. Chahine, L. Valade, Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex, New Journal of Chemistry, 2009, 33, 1268-1276
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A. Brausam, P. Á. Szilágyi, Z. Homonnay, J. Maigut, R. Meier, R. van Eldik, Detailed spectroscopic, thermodynamic and kinetic study of the interaction of hydrogen peroxide with FeIII(cdta) in comparison to FeIII(edta) in aqueous solution, Inorganic Chemistry, 2009, 48, 7864-84
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G. Agustí, S. Cobo, A. B. Gaspar, G. Molnár, N. O. Moussa, P. Á. Szilágyi, V. Pálfi, C. Vieu, J. A. Real and A. Bousseksou, Thermal and light-induced spin crossover phenomena in {FeII(4,4’- azopyridine)(MII(CN)4)}·nH2O (M = Ni, Pd or Pt) coordination polymers synthesized as microcrystalline powders and nano-patterned thin films, Chemistry of Materials, 2008, 20, 6721-6732
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P. Á. Szilágyi, S. Dorbes, G. Molnár, J. A. Real, Z. Homonnay, C. Faulmann and A. Bousseksou, Temperature and pressure effects on the spin state of ferric ions in the [Fe(sal2-trien)][Ni(dmit)2] spin crossover complex, Journal of Physics and Chemistry of Solids, 2008, 69, 2681-2686
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P. Á. Szilágyi, J. Madarász, E. Kuzmann, A. Vértes, G. Molnár, A. Bousseksou, V. K. Sharma, Z. Homonnay, Thermal Stability of the FeIIIEDTA Complex in its Monomeric Form, Thermochimimica Acta, 2008, 479, 53-58.
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Z. Homonnay, P. Á. Szilágyi, A. Vértes, E. Kuzman, V. K. Sharma, G. Molnár, A. Bousseksou; J.-M. Grenèche, A. Brausam, R. Meier, R. van Eldik, Iron chelates: a challenge to chemists and Mössbauer spectroscopists, Hyperfine Interactions, 2008, 182, 77-86.
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P. Á. Szilágyi, Z. Homonnay, R. Szalay, V. K. Sharma, A. Vértes, Mössbauer study of the autoxidation of ethylenediaminetetraacetato-ferrate(II), Structural Chemistry, 2007, 18, 121-125
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Z. Homonnay, P. Á. Szilágyi, E. Kuzmann, K. Varga, Z. Németh, A. Szabó, K. Radó, J. Schunk, P. Tilky, G. Patek, Corrosion study of heat exchanger tubes in pressurized water cooled nuclear reactors by conversion electron Mössbauer spectroscopy, Journal of Radioanalytical and Nuclear Chemistry, 2007, 85-90
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P. Tabero, A. Blonska-Tabero, P. Á. Szilágyi, Z. Homonnay, The investigations of phases with general formula M2FeV3O11, where M=Mg, Co, Ni, Zn by IR and Mössbauer spectroscopy, Journal of Physics and Chemistry of Solids, 2007, 68, 1087-1090
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C. Desroches, G. Pilet, P. Á. Szilágyi, G. Molnár, S. A. Borshch, A. Bousseksou, S. Parola, D. Luneau, Tetra- and Decanuclear Iron(II) Complexes of Thiacalixarene Macrocycles: Synthesis, Structure, Mössbauer Spectroscopy and Magnetic Properties, European Journal of Inorganic Chemistry, 2006, 357-365
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O. Graziani, P. Hamon, J-Y. Thépot, L. Toupet, P. Á. Szilágyi, G. Molnár, A. Bousseksou, M. Tilset, J. R. Hamon, Novel tert-Butyl-tris(3-hydrocarbylpyrazol-1-yl)borate ligands: Synthesis, Spectroscopic studies and Coordination chemistry, Inorganic Chemistry, 2006, 5661-5674
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K. Kovács, A. A. Kamnev, E. Kuzmann, Z. Homonnay, P. Á. Szilágyi, V. K. Sharma, A. Vértes, Mössbauer studies of iron(III)-(indole-3-alkanoic acids) systems in frozen aqueous solutions, Journal of Radioanalytical and Nuclear Chemistry, 2005, 513-517
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V. K. Sharma, P. Á. Szilágyi, Z. Homonnay, E. Kuzmann, A. Vértes, Mössbauer Investigation of Peroxo Species in the Iron(III)-EDTA-H2O2 System, European Journal of Inorganic Chemistry, 2005, 4393-4400
Patents
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R. J. Westerwaal, P. Á. Szilágyi, B. Dam, A Thin-Film Device for Detecting Hydrogen, 2014, WO2014098583 and NL2010031
Book chapters
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Z. Homonnay, N. Smith, V. K. Sharma, P. Á. Szilágyi, E. Kuzmann, Transformation of iron(VI) into iron(III) in the presence of chelating agents: a frozen solution Mössbauer study, In ACS S. S.: Ferrates: Synthesis, Properties, and Applications in Water and Wastewater Treatment, 2008, 985, 257-266
Peer-reviewed conference proceedings
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D. I. A. Millar, C. Barry, A. S. Cumming, D. J. Francis, A. K. Kleppe, W. G. Marshall, P. Á. Szilágyi and C. R. Pulham, Remarkable complexity of the metal azides: structural characterisation at extreme conditions, New Trends in Research of Energetic Materials, 2011, 2, 856-865
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Z. Homonnay, N. Smith, V. K. Sharma, P. Á. Szilágyi, E. Kuzmann, Insight into the aqueous chemistry of ferrate(VI) and ferrate(III): A frozen solution Mossbauer study, Preprints of Extended Abstracts presented at the ACS National Meeting, American Chemical Society, Division of Environmental Chemistry, 2006, 46, 593-598
